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- The Impact of High Particles Concentration in a Biofuel Droplet CombustionPublication . Mendes, Tomás S. M.; Ferrão, Inês; Mendes, Miguel; Moita, A. S.; Silva, A. R. R.Aviation is one of the largest transportation sectors and is operated on fossil fuels, being responsible for about 2% of global CO2 emissions. In order to reduce the environmental impact, biofuels emerged as a promising solution. Additionally, a possible approach to improve the performance of biofuels is to add nanoparticles, leading to the concept of nanofuel. The present work evaluates the nanofuel droplet combustion of a biofuel containing high aluminum particle concentrations. To enhance the nanofuel stability, a preliminary study focusing on the addition of a surfactant was mandatory. Particle size of 40 nm and three particle concentrations from 1.0 to 4.0 wt.% were considered. The results show that the oleic acid effectively improves the stability, and no visible oxidation of the nanoparticles was reported. Regarding the single droplet combustion, the observations show that the addition of nanoparticles promotes micro-explosions, contrary to the combustion of pure biofuel, and increases the overall droplet burning rate.
- Influence of aluminum nanoparticles in alternative fuel: Single droplet combustion experiments and modelingPublication . Ferrão, Inês; Mendes, Tomás; Mendes, Miguel; Moita, A. S.; Silva, A. R. R.In this work, the effect of adding aluminum nanoparticles on hydrotreated vegetable oil was investigated experimentally and numerically in terms of nanofuel stability and single droplet combustion. The purpose is to understand the phenomena related to isolated droplet combustion when metallic particles are added to a liquid biofuel. Falling droplet combustion experiments were conducted in a drop tube furnace at two different furnace temperatures (800 C and 1000 C) using a high-speed camera coupled with a high magnification lens to investigate the droplet size evolution as disruptive burning phenomena. In numerical terms, a simplified macroscopic model was developed to predict the burning behavior of isolated nanofuel droplets, considering hexadecane as a surrogate fuel for the biofuel. The results reveal that adding nanoparticles resulted in a departure from the -law. Moreover, an increase in the overall droplet burning rate was observed, and according to the numerical results, nanoparticle radiation absorption is the responsible mechanism. Micro-explosions occurred for all nanofuels, and this disruptive burning behavior substantially influenced the droplet lifetime.