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Application of the Pitzer theory to the evaluation of pH of the phthalate standard solution

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The pH value of the potassium hydrogen phthalate 0.05 mol.kg-1 has been detemined, using the Bates-Guggenheim convention and lhe Pitzer model for the calculation of the chloride íon activity coefficient. A comparison has been made between lhe two approaches.

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pH Phthalate buffer Bates-Guggenheim Pitzer's equations

Citation

Mendonça, A. and Ferra, M., 1997. Application of the Pitzer theory to the evaluation of pH of the phthalate standard solution. Portugalie Electrochimica Acta, 15, pp.245-249.

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Sociedade Portuguesa de Electroquímica

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