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Surface wettability modification of poly(vinylidene fluoride) and copolymer films and membranes by plasma treatment

2019Journal article Restricted access
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dc.contributor.authorCorreia, Daniela M.
dc.contributor.authorNunes-Pereira, João
dc.contributor.authorAlikin, Denis
dc.contributor.authorKholkin
dc.contributor.authorCarabineiro, S.A.C.
dc.contributor.authorRebouta, Luis
dc.contributor.authorRodrigues, Marco S.
dc.contributor.authorVaz, F.
dc.contributor.authorCosta, C. M.
dc.contributor.authorLanceros-Mendez, Senentxu
dc.date.accessioned2024-03-25T09:37:47Z
dc.date.available2024-03-25T09:37:47Z
dc.date.issued2019
dc.description.abstractThis manuscript reports on the modification of the surface wettability of poly (vinylidene fluoride) (PVDF) and PVDF copolymer films and membranes by plasma treatments at different conditions, under oxygen and argon atmospheres. It is shown that a more pronounced decrease of the contact angle after O2 plasma treatments is obtained, with a decrease of ∼20-30° for PVDF and its copolymers films, leading also to superhydrophilic membranes. This effect is related to a defluorination process, followed by the incorporation of oxygen atoms onto the surface of membranes that occurs during the surface modification. The influence of plasma treatments on surface morphology and topography was studied by atomic force microscopy, showing a decrease in the mean surface roughness with the plasma treatments, being more noticeable for Ar treatments. Finally, it is also shown that plasma treatments under Ar and O2 did not induce modifications in the physicochemical and thermal properties of PVDF and PVDF copolymers. The chemical reaction mechanism after plasma treatment is proposed for the different copolymers.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.doi10.1016/j.polymer.2019.02.042pt_PT
dc.identifier.urihttp://hdl.handle.net/10400.6/14293
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevierpt_PT
dc.relationPhysics Center of Minho and Porto Universities
dc.relationLarge-scale printing of novel photovoltaics based on Cu(In,Ga)Se2 chalcopyrite
dc.relationDevelopment of interactive books through smart and functional materials
dc.relationAdvanced Green Printed Batteries for Portable Devices
dc.relationIONIC ELECTROACTIVE POLYMERS FOR HIGH PERFORMANCE SENSOR AND ACTUATOR APPLICATIONS
dc.relationNew generation printable sensors and plasma actuators for flow control in aeronautics
dc.relationNovel nanomaterials and concepts for advanced rechargeable lithium- ion batteries
dc.relationNano-designed LSPR Thin Films Using GLAD in Reactive Magnetron Sputtering for Optical Sensing
dc.relationCICECO-Aveiro Institute of Materials
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/pii/S0032386119301818?via%3Dihubpt_PT
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/pt_PT
dc.subjectArgonpt_PT
dc.subjectPlasma treatmentspt_PT
dc.subjectOxygenpt_PT
dc.subjectPVDFpt_PT
dc.subjectPVDF copolymerspt_PT
dc.subjectSurface wettabilitypt_PT
dc.titleSurface wettability modification of poly(vinylidene fluoride) and copolymer films and membranes by plasma treatmentpt_PT
dc.typejournal article
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oaire.awardTitlePhysics Center of Minho and Porto Universities
oaire.awardTitleLarge-scale printing of novel photovoltaics based on Cu(In,Ga)Se2 chalcopyrite
oaire.awardTitleDevelopment of interactive books through smart and functional materials
oaire.awardTitleAdvanced Green Printed Batteries for Portable Devices
oaire.awardTitleIONIC ELECTROACTIVE POLYMERS FOR HIGH PERFORMANCE SENSOR AND ACTUATOR APPLICATIONS
oaire.awardTitleNew generation printable sensors and plasma actuators for flow control in aeronautics
oaire.awardTitleNovel nanomaterials and concepts for advanced rechargeable lithium- ion batteries
oaire.awardTitleNano-designed LSPR Thin Films Using GLAD in Reactive Magnetron Sputtering for Optical Sensing
oaire.awardTitleCICECO-Aveiro Institute of Materials
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oaire.citation.endPage147pt_PT
oaire.citation.startPage138pt_PT
oaire.citation.titlePolymerpt_PT
oaire.citation.volume169pt_PT
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person.givenNameLuis
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rcaap.embargofct0032-3861/ © 2019 Elsevier Ltd. All rights reserved.pt_PT
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
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