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Browsing ICI - FibEnTech | Documentos por Auto-Depósito by Author "Albuquerque, Antonio"
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- Analysis of the chemical properties of almond and walnut shells for use in earthworksPublication . Nouioua, Thamer; Marchiori, Leonardo; Albuquerque, Antonio; Silva, Flora Cristina Meireles; Pais, Luís Andrade; Cavaleiro, VictorAlmond (AS) and walnut shells (WS) have attracted the interest of scientific community due to the possibility of developing innovative eco-friendly materials. This work aims to analyze the chemical characteristics of AS, WS, a residual granitic soil (RGS) and two mix-tures of waste:soil (10:90% and 40:60%) for evaluating their compatibility for earthworks application. Results show that both wastes could be incorporated into RGS for improving its properties and additionally can remove some water pollutants due to the presence of K2O, CaO and SiO2. This application could reduce the need to use soil natural resources, incineration of both wastes or their deposition in sanitary landfills and can promote their valorization and even create value-added products in the scope of the circular economy. However, additional studies are needed for a better understanding of their potential for using in earthworks, namely leaching, solubilization and adsorption experiments.
- Biodegradability enhancement and detoxification of cork processing wastewater molecular size fractions by ozonePublication . Santos, Diana C.; Silva, Lúcia; Albuquerque, Antonio; Simões, Rogério; Gomes, A.C.Cork boiling wastewater pollutants were fractionated by sequential use of four ultrafiltration membranes and five fractions were obtained: four retentates (>100, 50-100, 20-50 and 10-20 kDa) and one permeate (<10 kDa); which were used to study the correlation of molecular size with biodegradability and toxicity before and after ozonation. The results show that molecular size is correlated with organic load and restrains biodegradability. The fraction with >100 kDa corresponds to 56% of the organic load and the one with <10 kDa only 8%. The biodegradability of fractions increased 182% with fractions molecular size reduction from >100 to < 10 kDa and the chemical oxygen demand (COD) was from 3436 to 386 mg L-1. For biodegradability enhancement the best outcome of ozonation was obtained with compounds having molecular size >20 kDa and range from 5% up to 175% for applied ozone doses to COD ratios between 0.15 and 0.38.
- Caracterização físico-química de cascas de amêndoas e nozes para valorização em obras de terraPublication . Marchiori, Leonardo; Nouioua, Thamer; Morais, Maria Vitoria; Silva, Flora Cristina Meireles; Albuquerque, Antonio; Andrade Pais, Luís; Cavaleiro, VictorOs resíduos agroindustriais têm sido investigados para aplicações de engenharia devido à sua elevada produção e ausência de valorização adequada face aos requisitos legais e de políticas e metas de sustentabilidade. O estudo das caraterísticas das cascas de amêndoas (CA) e nozes (CN) têm suscitado interesse na comunidade científica para desenvolver materiais alternativos e inovadores, com design sustentável, em várias aplicações. Este trabalho tem como objetivo caracterizar e analisar as propriedades físico-químicas de CA, CN e de um solo residual, bem como de duas misturas de cada resíduo com o solo, com 10% e 40% de cascas, para eventual aplicação em obras de terra. Os resultados mostraram que ambos os resíduos poderiam ser incorporados no solo para torná-los mais granulares e reduzir a densidade específica, além de terem potencial para remover alguns poluentes da água devido à presença de aluminosilicatos com K2O, CaO e SiO2. Esta aplicabilidade poderia reduzir a utilização de solos naturais em obras de terra, a incineração de ambas as cascas e sua deposição em aterros sanitários, podendo promover a sua valorização e criar produtos baseados em resíduos no âmbito da economia circular. No entanto, são necessários estudos adicionais para uma melhor compreensão do seu potencial para utilização em obras de terra, nomeadamente ensaios de lixiviação, degradação e adsorção.
- Energy Harvesting Opportunities in Geoenvironmental EngineeringPublication . Marchiori, Leonardo; Morais, Maria Vitoria; Studart, André; Albuquerque, Antonio; Andrade Pais, Luís; Ferreira Gomes, L.M.; Cavaleiro, VictorGeoenvironmental engineering involves defining solutions for complex problems, such as containment systems management, contaminant transport control, wastewater management, remediation of contaminated sites and valorization of geomaterials and wastes. In the last years, energy harvesting (EH)—or energy scavenging—methods and technologies have been developed to reduce the dependence on traditional energy sources, namely fossil fuels, and nuclear power, also responding to the increase in energy demands for human activities and to fulfill sustainable development goals. EH in geoenvironmental works and the surrounding soil and water environment includes a set of processes for capturing and accumulating energy from several sources considered wasted or unusable associated with soil dynamics; the stress and strain of geomaterials, hydraulic, vibrations, biochemical, light, heating and wind sources can be potential EH systems. Therefore, this work presents a review of the literature and critical analysis on the main opportunities for EH capturing, accumulating and use in geoenvironmental works, among basic electric concepts and mechanisms, analyzing these works in complex conditions involving biological-, chemical-, mechanical-, hydraulic- and thermal-coupled actions, concluding with the main investigation and challenges within geoenvironmental aspects for EH purposes.
- Environmental-chemical compatibility of granitic-mining waste for liner materialPublication . Marchiori, Leonardo; Studart, André; Morais, Maria Vitoria; Albuquerque, Antonio; Andrade Pais, Luís; Cavaleiro, VictorMining waste is generated from extracting mineral resources and, without proper disposal, can lead to negative environmental impacts because it can contain pollutants. Emerging studies of alternatives valorizing and reusing the residue through sustainable practices. Therefore, this research investigated the potential of granitic mining waste for waterproof liner materials, considering that most used liners, clays and geosynthetics, are increasingly scarce and costly solutions, respectively. This paper aims to analyze chemical compatibility, and microscopic structure of a granitic-mining mud to produce alternative material for liner construction. It was mixed in a clay at 25% and 50% ratio to develop a waste-based geocomposites. European limits for pollutants were respected for all mixtures, and the permeability remained less than 10-9m/s, which appears to be feasible for liners production. Thus, the valorization of mining waste as liner material arises as solution for creating new waste-based added-value product in the scope of circular economy.
- Geotechnical Characterization Methodology of Water Treatment Sludge for Production of Liner MaterialPublication . Marchiori, Leonardo; Morais, Maria Vitoria; Albuquerque, Antonio; Cavaleiro, VictorClayey soils and geosynthetic materials are used as low hydraulic conductivity layers and environmental protection barriers in civil engineering works for storing wastes as covering and bottom impermeabilization layer structures, known as liners. Future shortage of clay materials and geosynthetic’s high costs are usual problems, aligned with the need of prevention of environmental impacts associated to wastes by industry infiltrating into groundwater, sustainable solutions are needed. The reuse of industrial waste materials follows directives of the circular economy when this application is expected to reduce construction costs, help preserve natural resources, reduce the use of synthetic materials, reuse industrial waste materials, and contribute to sustainability. Water treatment sludges (WTS) are generated by water treatment plants mainly from periodic washing of the sedimentation tanks and filters and seems to be suitable for a geomaterial replacement. To make it feasible, the most significant factors that need more investigations are index properties, physical and mechanical behavior, chemical compaction and resistance, hydraulic conductivity, and leaching potential. A methodology for different ratios of WTS, soil, and with or without additive needing, along with a laboratorial analysis of water treatment sludge sample were proposed to ensure the expected results and parameters for liner alternative material.
- Geotechnical Characterization of Biomass Ashes for Soil Reinforcement and Liner MaterialPublication . Marchiori, Leonardo; Studart, André; Morais, Maria Vitoria; Albuquerque, Antonio; Andrade Pais, Luís; Boscov, Maria Eugenia Gimenez; Cavaleiro, VictorBiomass ashes (BA) have been intensively studied as amendments for soil in earthworks. This paper aimed to geotechnically characterize BA from pines and olive trees compared to the soil from Castelo Branco, Portugal. Namely, granulometry, specific gravity, Atterberg limits and optimal compaction values were obtained and analyzed in order to valorize the residue incorporated into soils. This work is part of broader efforts to develop an alternative material that can be used in hydraulic barriers as liners and for soil reinforcement. Thus, BA can contribute to reductions in weight and plasticity, and filling properties. Further studies are needed, particularly mechanical and hydraulic performance tests.
- Geotechnical Characterization of Vegetal Biomass Ashes Based Materials for Liner ProductionPublication . Marchiori, Leonardo; Studart, André; Morais, Maria Vitoria; Albuquerque, Antonio; Cavaleiro, VictorThis paper aims to evaluate geotechnically, chemically, mechanically, and hydraulically parameters of vegetal-based biomass ashes (VBA) and its soil incorporation with different ratios as potential liner material and soils strengthening. Composites were developed for testing with different ratios of VBA: soil, following 05:95, 10:90, 15:85, and 20:80%. All laboratorial testing program followed European standards. For geotechnical characterization, the following tests were performed for all mixtures, the soil and VBA: granulometric distribution, specific gravity and Atterberg limits. Chemical characterization was done by collecting pH values and energy-dispersive X-ray spectroscopy (EDS) parameters for elemental and oxides analysis. Also, x-ray diffraction (XRD) was done to evaluate all sample’s mineralogical description. In addition, mechanical analysis was conducted by analyzing expansibility, one-dimension consolidation through oedometer, and consolidated undrained (CU) triaxial test, along with falling head permeability for additional permeability analysis. Results have shown a finer granulometry and decrease of plasticity, 5% to non-plastic behavior, as higher amounts of VBA are introduced, exposing a filling-material behavior. EDS and XRD analysis indicate quartz, muscovite, orthoclase and calcite composition, and VBA could possibly have pozzolanic properties due to high silica-alum-ferric oxides amount. Mechanical parameters have shown a stabilization of VBA within the analyzed soil, exposing a slight reduction on settlements while increasing friction angle, 25–30º, and decreasing cohesion, 5–0 kPa. Permeability values have shown their feasibility for liners application, as found values characterizes all mixtures as low-permeability materials, especially introducing 5% of the residue into soil which values were below 10–9 m/s. Thus, the incorporation of VBA into soils paves a solid alternative for reusing this material in varied applications, as the analyzed soft soil has been geotechnically enhanced. Additional analysis, mainly pozzolanicity levels and leachability tests, can contribute for this on-going study to stablish VBA as a feasible material for the industry.
- Geotechnical Characterization of Water Treatment Sludge for Liner Material Production and Soft Soil ReinforcementPublication . Marchiori, Leonardo; Studart, André; Albuquerque, Antonio; Cavaleiro, Victor; Silva, AbilioA water treatment sludge (WTS) was characterized in order to evaluate if its properties would be suitable for use as liner of earthworks or for strengthening a clay soil. A WTS and a clayey soil was characterized in terms of granulometry, cumulative volumes, specific surface, density, plastic limit, liquid limit, water content, hydraulic conductivity, and characteristics of compaction (optimal water content and dry density). This study aimed to exhibit and evaluate these investigated parameters of WTS, soft soil and mixed proportions between the materials for liners’ material production while evaluating soft soils’ reinforcement feasibility. The results have shown WTS’s contribution with its fine granulometry and compaction characteristics, indicating filling properties and possible feasibility as soft soils additions for liners’ material production while being applicable for soils‘ reinforcements, corroborating with existing literature on the subject. Thus, the currently developed investigation has exposed WTS as a potential addition for these applications while also attending society’s new demands towards a more sustainable future.
- Granitic Mining Waste Feasibility for Liner Material ProductionPublication . Marchiori, Leonardo; Albuquerque, Antonio; Cavaleiro, VictorThis work aims to characterize geotechnically and mechanically a granitic mine waste (MW), a clayey soil, and two mixtures of M:soil with 50% and 25% of (dry mass), looking to evaluate its feasibility for liner material production. Samples of MW, soil, M:soil(50:50%) M:soil(25:75%) were analysed in terms of specific gravity (GS), coarse and fine portions granulometry distributions, Atterberg limits (WL and WP), Normal Proctor compaction parameters (wopt and ρd,opt), oedometer compressibility test, consolidated undrained (CU) triaxial compression and hydraulic conductivity (k). MW showed finer granulometry, and higher plasticity than the soil, possibly showing filling properties for the mixtures, lower GS and ρd,opt indicating weight-reduction for a new liner material development. Furthermore, k values can reach the requirement for liner application of a minimum of 10-9 m/s, although it needs more investigation on leachability capacity, cation exchange capacity and chemical compatibility in case addition of chemicals are needed for improving mixtures properties for liner material.