| Nome: | Descrição: | Tamanho: | Formato: | |
|---|---|---|---|---|
| 316.71 KB | Adobe PDF |
Orientador(es)
Resumo(s)
Electroepoxidation of synthetic alkenes (styrene, trans-stilbene and trans-b-methylstyrene) and of some natural terpenes (limonene, terpinolene, geraniol, a-terpinene, g-terpinene and a-terpineol) mediated by sodium bromide was performed in MeCN:H2O (4:1) at platinum electrodes. The indirect electrochemical oxidation of the olefins led to the corresponding epoxides in yields ranging from 23% to 79%.
Descrição
Palavras-chave
Electrochemical epoxidation Sodium bromide Alkenes Terpenes
Contexto Educativo
Citação
Inês, M., Mendonça, A. J., Esteves, A. P., Mendonça, D. I., & Medeiros, M. J. (2009). Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide. Comptes Rendus Chimie, 12(8), 841-849. doi:10.1016/j.crci.2008.10.014
Editora
Elsevier Masson SAS