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Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
Publication . Inês, Massuquinini; Mendonça, António; Esteves, Ana P.; Mendonça, Dina; Medeiros, Maria J.
Electroepoxidation of synthetic alkenes (styrene, trans-stilbene and trans-b-methylstyrene) and of some natural terpenes (limonene, terpinolene, geraniol, a-terpinene, g-terpinene and a-terpineol) mediated by sodium bromide was performed in MeCN:H2O (4:1) at platinum electrodes. The indirect electrochemical oxidation of the olefins led to the corresponding epoxides in yields ranging from 23% to 79%.
2009-01-08Artigo científico Acesso restrito Ver mais