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Browsing FE - DECA | Documentos por Auto-Depósito by Author "Albuquerque, Antonio"
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- Analysis of constructed wetland performance for irrigation reusePublication . Monte, Helena Marecos do; Albuquerque, AntonioMost of the wastewater treatment systems in small rural communities of the Cova da Beira region (Portugal) consist of constructed wetlands (CW) with horizontal subsurface flow (HSSF). It is believed that those systems allow the compliance of discharge standards as well as the production of final effluents with suitability for reuse. Results obtained in a nine-month campaign in an HSSF bed pointed out that COD and TSS removal were lower than expected. A discrete sampling also showed that removal of TC, FC and HE was not enough to fulfill international irrigation goals. However, the bed had a very good response to variation of incoming nitrogen loads presenting high removal of nitrogen forms. A good correlation between mass load and mass removal rate was observed for BOD5, COD, TN, NH4-N, TP and TSS, which shows a satisfactory response of the bed to the variable incoming loads. The entrance of excessive loads of organic matter and solids contributed for the decrease of the effective volume for pollutant uptake and therefore, may have negatively influenced the treatment capability. Primary treatment should be improved in order to decrease the variation of incoming organic and solid loads and to improve the removal of COD, solids and pathogenic. The final effluent presented good physical–chemical quality to be reused for irrigation, which is the most likely application in the area.
- Analysis of the chemical properties of almond and walnut shells for use in earthworksPublication . Nouioua, Thamer; Marchiori, Leonardo; Albuquerque, Antonio; Silva, Flora Cristina Meireles; Pais, Luís Andrade; Cavaleiro, VictorAlmond (AS) and walnut shells (WS) have attracted the interest of scientific community due to the possibility of developing innovative eco-friendly materials. This work aims to analyze the chemical characteristics of AS, WS, a residual granitic soil (RGS) and two mix-tures of waste:soil (10:90% and 40:60%) for evaluating their compatibility for earthworks application. Results show that both wastes could be incorporated into RGS for improving its properties and additionally can remove some water pollutants due to the presence of K2O, CaO and SiO2. This application could reduce the need to use soil natural resources, incineration of both wastes or their deposition in sanitary landfills and can promote their valorization and even create value-added products in the scope of the circular economy. However, additional studies are needed for a better understanding of their potential for using in earthworks, namely leaching, solubilization and adsorption experiments.
- Application of GIS-based multi-criteria analysis for site selection of aquifer recharge with reclaimed waterPublication . Pedrero, Francisco; Albuquerque, Antonio; Monte, Helena Marecos do; Cavaleiro, Victor; Alarcon, Juan JoseReclaimed water from small wastewater treatment facilities in the rural areas of the Beira Interior region (Portugal) may constitute an alternative water source for aquifer recharge. A 21-month monitoring period in a constructed wetland treatment system has shown that 21,500 m3 year−1 of treated wastewater (reclaimed water) could be used for aquifer recharge. A GIS-based multi-criteria analysis was performed, combining ten thematic maps and economic, environmental and technical criteria, in order to produce a suitability map for the location of sites for reclaimed water infiltration. The areas chosen for aquifer recharge with infiltration basins are mainly composed of anthrosol with more than 1 m deep and fine sand texture, which allows an average infiltration velocity of up to 1 m d−1. These characteristics will provide a final polishing treatment of the reclaimed water after infiltration (soil aquifer treatment (SAT)), suitable for the removal of the residual load (trace organics, nutrients, heavy metals and pathogens). The risk of groundwater contamination is low since the water table in the anthrosol areas ranges from 10 m to 50 m. On the other hand, these depths allow a guaranteed unsaturated area suitable for SAT. An area of 13,944 ha was selected for study, but only 1607 ha are suitable for reclaimed water infiltration. Approximately 1280 m2 were considered enough to set up 4 infiltration basins to work in flooding and drying cycles.
- Avaliação do potencial de reúso de águas residuais tratadas no Bairro de Palha Sé e no Aeroporto Internacional da cidade da Praia (Cabo Verde)Publication . Cabral, Nay Even Sanches; Albuquerque, Antonio; Leitão, SandersonA construção de um novo bairro em Palha Sé (cidade da Praia, ilha de Santiago, Cabo Verde) e a necessidade de se tratarem as águas residuais aí produzidas, suscitaram o interesse no seu reúso no próprio bairro e no Aeroporto Internacional da Praia o que poderia levar a poupanças consideráveis no consumo de água dessalinizada e de custos associados à sua utilização para fins onde não é necessário utilizar água potável. Foi realizada uma estimativa do volume de águas residuais gerado no bairro para 2025, 2030 e 2050, bem como os seus consumos de água potável (para irrigação de espaços verdes e lavagem de áreas pavimentadas) e no aeroporto (para irrigação de espaços verdes, descarga de sanitários, lavagem de pavimentos, arruamentos, pistas, estacionamentos, passeios públicos, aeronaves, veículos e equipamentos de apoio e para simulação de combate a incêndios), para o mesmo período. Os resultados mostram, para um horizonte de 25 anos, que 70% (2025), 60% (2035) e 41% (2050) das águas residuais produzidas no bairro, após tratamento superior ao secundário, poderiam ser reusadas em ambos os espaços. A irrigação seria o maior consumidor no bairro (71% (2025), 66% (2035) e 57% (2050)), enquanto as lavagens levariam o maior consumo no aeroporto (84% (2025), 81% (2035) e 81% (2050)). No conjunto, a irrigação e as lavagens em ambos os espaços consumiriam 96% (2025), 95% (2035) e 95% (2050).
- Biodegradability enhancement and detoxification of cork processing wastewater molecular size fractions by ozonePublication . Santos, Diana C.; Silva, Lúcia; Albuquerque, Antonio; Simões, Rogério; Gomes, A.C.Cork boiling wastewater pollutants were fractionated by sequential use of four ultrafiltration membranes and five fractions were obtained: four retentates (>100, 50-100, 20-50 and 10-20 kDa) and one permeate (<10 kDa); which were used to study the correlation of molecular size with biodegradability and toxicity before and after ozonation. The results show that molecular size is correlated with organic load and restrains biodegradability. The fraction with >100 kDa corresponds to 56% of the organic load and the one with <10 kDa only 8%. The biodegradability of fractions increased 182% with fractions molecular size reduction from >100 to < 10 kDa and the chemical oxygen demand (COD) was from 3436 to 386 mg L-1. For biodegradability enhancement the best outcome of ozonation was obtained with compounds having molecular size >20 kDa and range from 5% up to 175% for applied ozone doses to COD ratios between 0.15 and 0.38.
- Biological and technical study of a partial-SHARON reactor at laboratory scale: effect of hydraulic retention timePublication . Gonzalez-Martinez, A.; Calderon, K.; Albuquerque, Antonio; Hontoria, E.; Gonzalez-Lopez, J.; Guisado, I.; Osorio, FranciscoThis study was on the technical and biological characteristics of a partial-SHARON submerged-filter bioreactor of 3 L. The main focus was the influence of the hydraulic retention time (HRT) on biofilms. For this purpose, we used molecular tools based on the partial 16S rRNA genes. The results showed that the HRT may affect the nitrification processes of a bioreactor using synthetic wastewater containing 600 mg/L of ammonia. It was found that an HRT of 0.5 day transformed 100 % of the ammonium into nitrite. However, when the HRT was decreased to 0.4 day, there was a significant reduction (35 %) in the quantity of ammonia transformed, which confirmed the complexity of the system operation. Moreover, a PCR-TGGE approach highlighted the differences observed. The results obtained showed that an HRT of 0.5 day reduced bacterial biodiversity in the biofilms, which were mainly formed by Nitrosomonas and Diaphorobacter. In contrast, an HRT of 0.4 day facilitated the formation of heterogeneous biofilms formed by nitrifying bacteria, such as Nitrosomonas sp., Nitrosospira sp., and Nitrosovibrio sp.).
- Caracterização físico-química de cascas de amêndoas e nozes para valorização em obras de terraPublication . Marchiori, Leonardo; Nouioua, Thamer; Morais, Maria Vitoria; Silva, Flora Cristina Meireles; Albuquerque, Antonio; Andrade Pais, Luís; Cavaleiro, VictorOs resíduos agroindustriais têm sido investigados para aplicações de engenharia devido à sua elevada produção e ausência de valorização adequada face aos requisitos legais e de políticas e metas de sustentabilidade. O estudo das caraterísticas das cascas de amêndoas (CA) e nozes (CN) têm suscitado interesse na comunidade científica para desenvolver materiais alternativos e inovadores, com design sustentável, em várias aplicações. Este trabalho tem como objetivo caracterizar e analisar as propriedades físico-químicas de CA, CN e de um solo residual, bem como de duas misturas de cada resíduo com o solo, com 10% e 40% de cascas, para eventual aplicação em obras de terra. Os resultados mostraram que ambos os resíduos poderiam ser incorporados no solo para torná-los mais granulares e reduzir a densidade específica, além de terem potencial para remover alguns poluentes da água devido à presença de aluminosilicatos com K2O, CaO e SiO2. Esta aplicabilidade poderia reduzir a utilização de solos naturais em obras de terra, a incineração de ambas as cascas e sua deposição em aterros sanitários, podendo promover a sua valorização e criar produtos baseados em resíduos no âmbito da economia circular. No entanto, são necessários estudos adicionais para uma melhor compreensão do seu potencial para utilização em obras de terra, nomeadamente ensaios de lixiviação, degradação e adsorção.
- Cracking and desiccation of water treatment sludge for incorporation into soils for alternative liner material productionPublication . Marchiori, Leonardo; Morais, Maria Vitoria; Albuquerque, Antonio; Ferreira-Gomes, L.M.; Cavaleiro, VictorCracks may lead to hydraulic failure in soils due to increase of hydraulic conductivity which facilitate water infiltration, impacting negatively for liner materials. Therefore, cracking and desiccation investigation on liner material is advised. Water treatment sludge (WTS) is a by-product resulting from water treatment plants, and it seems to be suitable for geotechnical applications and soil replacement due to hydraulic latent properties, chemical similarities to soils, and mechanical behaviour. In this work WTS samples were incorporated into soil in different ratios – 05%; 10%; 15% and 20% of waste in dried mass of the geocomposites. The four mixtures, a soil sample and a WTS were tested according to the following procedure: two different circular Petri dishes samples were used, 5mm(H5) and 10mm(H10), and two cylindrical compacted samples with 65-70mm of diameter and 20-140mm of height (EDO-TRI, respectively) - dried for 10 days in controlled temperature and humidity. Water release curves (WRC), digital images correlation supported Crack Intensity Factor (CIF) index results were obtained for each material. Cracking behaviour results were compared with the permeability through falling head laboratorial tests, and studies around WTS ratio. Composites with 10% and 15% had the best results, showing no cracks during Petri dishes procedures for H10, in addition, the permeability for these materials reached the maximum for liner production – 10-9 m/s according to European and American directives - making possible the development of an alternative and feasible liner material.
- Critical review of industrial solid wastes as barrier material for impermeabilization of storage waste facilitiesPublication . Marchiori, Leonardo; Albuquerque, AntonioNatural materials (e.g. clays) and synthetic materials (e.g. geosynthetics) are commonly applied as low hydraulic conductivity layers and environmental protection barriers in civil engineering works for storing solid wastes and wastewaters (e.g. solid waste landfilling, wastewater lagoons and mining waste ponds) for both covering and bottom impermeabilization of soils structures. However, due to a future shortage of clay materials and their high transport costs, in addition to geosynthetics generating more waste and presenting high costs, two needs emerge: reducing the amount of waste generated and developing strategies for preventing this waste from infiltrating the soil and ground water. One of the possible solutions consists in the use of some geotechnically applicable residues to prevent soil infiltration. Thus, the use of waste materials is particularly advantageous since it can considerably reduce construction costs, help preserve natural resources, and contribute to sustainability by turning “waste” materials into “valuable resource”. Many by-products of industry and waste (fly and bottom coal ash, blast furnace slag, foundry sands, water treatment plant sludge, agroindustry ashes, incinerated biomass ash, red mud, drilling mud and mine waste, among others) have been extensively studied as to their suitability as a geomaterial and showed promising results for use in waterproofing barriers (liners). The most significant factors that depend on hydraulic conductivity are index properties, compaction characteristics and compressive strength, so, in this aspect, hydraulic, mechanical, physical-chemical and mineralogical properties determine the valorisation, or not, of the waste as liner material. Industrial wastes and geocomposites acting as hydraulic barriers material literature were reviewed and analysed its actual applications such as lack of researches suggesting future investigations.
- Effect of aeration on steady-state conditions in non- and partially aerated low-loaded biofilterPublication . Albuquerque, Antonio; Gonzalez-Martinez, A.; Osorio, FranciscoExcessive growth of biomass and retention of solids associated with air bubbles lead to bed clogging, which affects the biofilters' performance. Two experiments were carried out in a submerged biofilter at the flow velocity of 0.5 m h(-1), for an organic loading rate of 51 g C m(-3) h(-1) and a nitrogen loading rate of 13 g NH4-N m(-3) h(-1), one with the biofilter not aerated, the other with the biofilter partially aerated. The results showed that the higher head losses occurred in the upper section of the biofilter, where there was a greater biomass development and a higher removal of organic carbon, ammonia and solids, with the maximum allowed head loss being reached in 16 and 8 days. In any case, the steady-state conditions were achieved after 2 days and were interrupted on the tenth day of experiment E1 and on the fifth day of experiment E2. This allowed defining different operating cycles that enabled an average organic removal rate of 12.7 g C m(-3) h(-1) (27 %) and an average ammonia removal rate of 1.1 g NH4-N m(-3) h(-1) (9 %) without aeration, and of 35.8 g C m(-3) h(-1) (76 %) and 6.3 g NH4-N m(-3) h(-1) (51 %) with aeration. Regardless of the aeration conditions, more than 90 % of TOC and NH4-N removal occurred in the upper section. After the backwashing cycle, the biofilter returned to steady-state conditions in 6 h (without aeration) and 7 h (with aeration).