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- Optimização da Técnica de Preparação de Amostras de Betões Refractários Auto-Escoantes de Alumina Sem Cimento Para Observação MicroscópicaPublication . Silva, Abílio P.; Gomes, Ana; Segadães, Ana Maria; Devezas, TessalenoA preparação de amostras para a observação de superfícies em microscopia requer um procedimento de corte, rectificação e polimento rigoroso que obedeça a requisitos sistemáticos de avaliação da qualidade superficial. Neste trabalho, um novo material constituído por 100% de alumina, mas de ingredientes (matriz e agregado) com características distintas obrigou, à implementação de uma nova receita de polimento e de realce dos contrastes entre os elementos estruturais presentes. Assim, apresenta-se um procedimento optimizado para a preparação das amostras de betões refractários auto-escoantes de alumina sem cimento para análise da microestrutura em microscópio metalográfico em complementaridade com o microscópio electrónico de varrimento.
- Designing particle sizing and packing for flowability and sintered mechanical strengthPublication . Silva, Abílio P.; Pinto, Deesy G.; Segadães, A M; Devezas, TessalenoIn this work, alumina powders in five different commercially available size ranges were used to prepare various refractory castable mixtures, defined using the statistical design of mixture experiments (STATISTICA, StatSoft Inc.) and the EMMA 3.3 software (Elkem Materials). Those mixtures were characterized for packing density, Andreasen particle size distribution modulus (q), flowability and after sintering properties, in order to investigate the relationships between these variables. The optimization of matrix and aggregate sizes and matrix-aggregate proportion, subjected to different property requirements, brought to light the relationships between q, specific surface area (SSA) and maximum paste thickness (MPT). Those relationships were investigated for three fundamental processing steps, namely, dry powders, fresh paste and consolidated dried and sintered bodies. The optimized all-alumina castable was found to require 47.5wt.% of a fine size matrix with high flowability, which provides the necessary flow bed for 52.5wt.% of coarse aggregates, resulting in a gap-sized particle size distribution, and presented a fresh paste flowability index above 130% with minimum added water (28mg/m2) and sintered modulus of rupture above 50MPa.
- Energy scenarios: Toward a new energy paradigmPublication . Devezas, Tessaleno; LePoire, David; Matias, João; Silva, AbílioPrimary energy sources exhibited regular long-term logistic substitution trends from the mid-19th century through the third quarter of the 20th century. This analysis, based on an extension of the Fisher–Pry substitution model, accounted for the observed historical shifts of primary energy use from sources of wood, coal, oil, natural gas, and nuclear. In the mid1980s the substitution dynamics was replaced by a relatively constant contribution from oil, natural gas, coal, nuclear power, and hydropower. However, a major factor in energy use dynamics in this recent period was substitution of conservation and efficiency for actual fuel use. The energy efficiency is measured as the ratio of economic activity to the rate of energy use (energy intensity). To incorporate these data into the logistic analysis, a method for estimating the fraction of energy saved by the increased efficiency was used. With this interpretation, energy efficiency fits within the substitution model. Furthermore, to identify indications of future energy scenarios, as well as to test the logistic substitution analysis, another statistical approach using ternary diagrams was developed. The consistent results from both logistic substitution and statistical analysis are compared with recent energy projections, trends in decarbonization, Kondratieff waves, and other efficiency measures. While the specific future mix of renewables and nuclear energy sources is uncertain, the more general logistic dynamics pattern of the energy system seems to be continuing as it has for about 150 years now.
- Mechanical Characterization of Composites with Embedded Optical FibersPublication . Silva, José M.A.; Devezas, Tessaleno; Silva, Abílio; Ferreira, José A. M.The purpose of this investigation is to evaluate quantitatively and comparatively the effect of embedding optical fibers (OF) on the mechanical behavior of a carbon fiber-epoxy composite in order to verify whether their presence can possibly degrade the mechanical performance of the host material. The existing literature on this subject is not conclusive about the nature and intensity of this effect. Adding more reliable data to our systematic study contributes to this discussion favoring the conclusion about a harmful influence as a consequence of optical fiber embedment. Three kinds of mechanical tests have been performed in this work: impact tests, static flexural tests, and fatigue tests. The results of some experiments point to a possible detrimental influence related to the presence of the OF, being it different in nature and intensity for each of these tests. The mechanical behavior in static loading conditions seems to be not significantly affected as a consequence of the presence of the OF, while that in impact and fatigue tests are strongly affected, even though this influence being physically distinct from each other. Based on these results, some discussion is made about the possible failure mechanisms that can explain the detected differences.
- Aplicação de métodos estatísticos na otimização da densidade de empacotamento de distribuições de pós de aluminaPublication . Silva, Abílio P.; Segadães, A M; Devezas, TessalenoFatores como a distribuição granulométrica e a morfologia condicionam as propriedades físicas de sistemas particulados (e.g. misturas de pós, pastas, concretos refratários), entre as quais a densidade de empacotamento. Podem ser encontrados, na literatura, vários modelos para a otimização da distribuição de tamanhos de partículas que maximiza o empacotamento, todos desenvolvidos para sistemas de esferas perfeitas (e.g. Furnas, Andreasen, Alfred). Neste trabalho, pós de alumina comercial (reativa e tabular) foram separados em nove frações granulométricas e, recorrendo a dois procedimentos distintos, construíram-se seis sistemas ternários diferentes e complementares de tamanhos de partículas. Usando a metodologia das superfícies de resposta e técnicas de análise estatística afins (programa de cálculo Statistica) obteve-se, em ambos os casos, a distribuição granulométrica que maximiza a densidade de empacotamento. Por comparação com as distribuições granulométricas teóricas, ficou demonstrada a validade do modelo teórico de Alfred para esferas perfeitas. Os resultados obtidos demonstram, assim, que o efeito prejudicial da não esfericidade das partículas pode ser, na realidade, compensado pela otimização da distribuição granulométrica global.
- Effect of particle size distribution and calcium aluminate cement on the rheological behaviour of all-alumina refractory castablesPublication . Silva, Abílio P.; Segadães, A M; Pinto, Deesy G.; Oliveira, Luiz A.; Devezas, TessalenoPrevious works based on statistical design of experiments (DoE) defined a model all-alumina self-flow refractory castable (SFRC) with optimized particle size distribution for simultaneous high flowability index (FI) and superior post-sintering performance. This work compares the SFRC rheological behaviour and setting time with those of alternative all-alumina castables with different Andreasen aggregate particle size distribution modulus, and of the equivalent castables containing calcium aluminate cement. The model castable showed Bingham behaviour with low yield stress, viscosity and thixotropy, guaranteeing easier casting and less wear in the casting and/or projection equipment. However, as the coarse particle fraction increases, the castable flow tends to be non-linear and changes from Bingham to Herschel–Bulkley. The cement containing castables quickly loose flowability despite the applied shear. This work confirmed previous conclusions based on FI measurements and demonstrates the adequacy of the use of FI values in the calculation of FI response surface by DoE.
- Thermomechanical evaluation of self-flowing refractory castables with and without the addition of aluminate cementPublication . Pinto, Deesy G.; Silva, Abílio P.; Segadães, A M; Devezas, TessalenoMuch has been discussed about the advantages regarding the thermomechanical performance of self-flow refractory castables (SFRC), with very little or no addition of calcium aluminate cement (CAC) when compared to conventional composites with cement. Previous works demonstrated that a 100% alumina SFRC with optimized particle size distribution simultaneously results in high-flowability fresh paste and high mechanical strength. In this work, the thermomechanical behaviour of zero-cement ceramic matrix is compared to that of the equivalent composite with 1% CAC content. The results show that the differences in performance can be related to differences in hydration mechanisms, namely the formation sequence of calcium aluminate hydrates, which results in increased open porosity. With lower dried strength, the all-alumina castable presents lower porosity, higher mechanical strength and uncompromised thermal shock resistance, being a valuable option when fast drying or rough green handling can be avoided.