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  • High deformation multifunctional composites: materials, processes, and applications
    Publication . Costa, Pedro; Nunes-Pereira, João; Rial Tubio, Carmen; Dios, Jose Ramón; Lanceros-Mendez, Senentxu
    Structural health monitoring (SHM) is a nondestructive process of collecting and analyzing data from structures to evaluate their conditions and predict the remaining lifetime. Multifunctional sensors are increasingly used in smart structures to self-sense and monitor the damages through the measurements of electrical resistivity of composite materials. Polymer-based sensors possess exceptional properties for SHM applications, such as low cost and simple processing, durability, flexibility, and excellent piezoresistive sensitivity. Thermoplastics, thermoplastic elastomers, and elastomer matrices can be combined with conductive nanofillers to develop piezoresistive sensors. Polymer, reinforcement fillers, processing and design have critical influences in the overall properties of the composite sensors. Together with the properties of the functional composites, environmental concerns are being increasingly relevant for applications, involving advances in materials selection and manufacturing technologies. In this scenario, additive manufacturing is playing an increasing role in modern technological solutions. Stretchable multifunctional composites applications include piezoresistive, dielectric elastomers (mainly for actuators), thermoelectric or magnetorheological materials. In the following sections, piezoresistive materials and applications will be mainly addressed based on their increasing implementation into applications.
  • Piezoelectric Energy Production
    Publication . Nunes-Pereira, João; Costa, Pedro; Lanceros-Mendez, Senentxu
    The concept of piezoelectric energy production is based on energy-harvesting devices using generation materials such as single crystals, ceramics, polymers, and composites. These production systems can harvest wasted environmental energy and convert it essentially into electrical energy. There are different nano- and microscale power harvesters which are increasingly useful for powering mobile electronics and low-power devices, even in hardly accessible areas. Despite many efforts in the development of new materials, the most widely used materials in device applications remain the ceramics of the lead zirconate titanate family, since they still present the higher output performances in the range of milliwatts of generated power.
  • Antimicrobial and Antibiofilm Properties of Fluorinated Polymers with Embedded Functionalized Nanodiamonds
    Publication . Nunes-Pereira, João; Costa, Pedro; Fernandes, Liliana; Carvalho, Estela O.; Fernandes, Margarida M.; Carabineiro, S.A.C.; Buijnsters, Josephus; Rial Tubio, Carmen; Lanceros-Mendez, Senentxu
    Environmentally resilient antimicrobial coatings are becoming increasingly required for a wide range of applications. For this purpose, nanocomposite thin films of poly(vinylidene fluoride) (PVDF) filled with several types of functionalized nanodiamonds (NDs) were processed by solvent casting. The effects of ND inclusion and functionalization in their morphological, structural, optical, thermal, and electrical properties were evaluated taking into account the type of the nanofiller and a concentration up to 2 wt %. The morphology, structure, and thermal features of the polymer matrix are governed by the processing conditions, and no noticeable changes occurred due to the presence of the ND fillers. The polymer crystallized mainly in the α phase with a crystallinity of ≈60%. In turn, the optical transmittance from 200 to 800 nm and the dielectric constant effectively depended on the ND type and content. The inclusion of the ND particles effectively provided antimicrobial properties to the films, which depended on the ND functionalization. This study thus shows that the incorporation of functionalized NDs into PVDF allows the development of antimicrobial coatings with tailorable optical and dielectric properties, which could be of great importance to face nowadays pandemic crisis scenario.
  • Recent Progress on Piezoelectric, Pyroelectric, and Magnetoelectric Polymer‐Based Energy‐Harvesting Devices
    Publication . Costa, Pedro; Nunes-Pereira, João; Pereira, Nelson; Castro, Nélson; Gonçalves, Sérgio; Lanceros-Mendez, Senentxu
    Energy harvesting from the environment based on electroactive polymers has been increasing in recent years. Ferroelectric polymers are used as mechanical-to-electrical energy transducers in a wide range of applications, scavenging the surrounding energy to power low-power devices. These energy-harvesting systems operate by taking advantage of the piezoelectric, pyroelectric, and magnetoelectric properties of the polymers, harvesting wasted environmental energy and converting it mainly into electrical energy. There have been developed different nano- and micro-scale power harvesters with an increasing interest for powering mobile electronics and low-power devices, including applications in remote access areas. Novel electronic devices are developed based on low-power solutions, and therefore, polymer-based materials represent a suitable solution to power these devices. Among the different polymers, the most widely used in the device application is the poly(vinylidene fluoride) (PVDF) family, due to its higher output performance.